ON THE LIMITING RADIAL-DISTRIBUTION FUNCTION FOR HYDROGENIC ORBITALS

Authors
Citation
Ls. Bartell, ON THE LIMITING RADIAL-DISTRIBUTION FUNCTION FOR HYDROGENIC ORBITALS, Journal of mathematical chemistry, 19(3-4), 1996, pp. 401-403
Citations number
4
Categorie Soggetti
Chemistry,Mathematics
ISSN journal
02599791
Volume
19
Issue
3-4
Year of publication
1996
Pages
401 - 403
Database
ISI
SICI code
0259-9791(1996)19:3-4<401:OTLRFF>2.0.ZU;2-N
Abstract
An exact reduced limiting expression for the generalized radial distri bution function D-n(r) is derived and compared with quantum distributi ons for various degrees of excitation. It represents the quantum resul t at large quantum numbers significantly better than a prior empirical representation of the universal reduced distribution and gives a some what larger electronic partition function for the hydrogen atom than t hat based on the previous distribution.