TRIBUTYLSTANNYL 4-TRIBUTYLSTANNYLBUT-3-ENOATE - A USEFUL C-4 HOMOLOGATING AGENT - APPLICATION TO THE SYNTHESIS OF ARYL IODOLACTONES

Citation
J. Thibonnet et al., TRIBUTYLSTANNYL 4-TRIBUTYLSTANNYLBUT-3-ENOATE - A USEFUL C-4 HOMOLOGATING AGENT - APPLICATION TO THE SYNTHESIS OF ARYL IODOLACTONES, Tetrahedron letters, 37(42), 1996, pp. 7507-7510
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
37
Issue
42
Year of publication
1996
Pages
7507 - 7510
Database
ISI
SICI code
0040-4039(1996)37:42<7507:T4-AUC>2.0.ZU;2-1
Abstract
Tributylstannyl 4-tributylstannylbut-3-enoate, readily prepared by rad ical hydrostannation, is used for the transfer of a but-3-enoic acid s ynthon. Some of the potentialities of this synthon are established by the synthesis of aryl iodolactones or tetralones (one of them is a key intermediate for ABT-200 synthesis). Copyright (C) 1996 Published by Elsevier Science Ltd