AN EFFICIENT PREPARATION OF PERI-HYDROXY DIHYDROQUINONE DERIVATIVES THROUGH A PUMMERER-TYPE REARRANGEMENT OF SILYLENE-PROTECTED PERI-HYDROXY AROMATIC SULFOXIDES
Y. Kita et al., AN EFFICIENT PREPARATION OF PERI-HYDROXY DIHYDROQUINONE DERIVATIVES THROUGH A PUMMERER-TYPE REARRANGEMENT OF SILYLENE-PROTECTED PERI-HYDROXY AROMATIC SULFOXIDES, Tetrahedron letters, 37(42), 1996, pp. 7545-7548
Silylene protection of two dihydroxy groups of the peri-hydroxy aromat
ic sulfides 6a-f was essential for the subsequent Pummerer-type reacti
on. The overall process provided a novel and efficient approach to the
peri-hydroxy dihydroquinone derivatives 9a-f. Copyright (C) 1996 Else
vier Science Ltd