NEW MONODENTATE CHIRAL PHOSPHINE THYL-9-PHENYL-9-PHOSPHABICYCLO[3.3.1]NONANE(9-PBN) - APPLICATION TO ASYMMETRIC ALLYLIC SUBSTITUTION-REACTION

Authors
HAMADA Y SETO N OHMORI H HATANO K
Citation
Y. Hamada et al., NEW MONODENTATE CHIRAL PHOSPHINE THYL-9-PHENYL-9-PHOSPHABICYCLO[3.3.1]NONANE(9-PBN) - APPLICATION TO ASYMMETRIC ALLYLIC SUBSTITUTION-REACTION, Tetrahedron letters, 37(42), 1996, pp. 7565-7568
Citations number
45
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
42
Year of publication
1996
Pages
7565 - 7568
Database
ISI
SICI code
0040-4039(1996)37:42<7565:NMCPT>2.0.ZU;2-M
Abstract
New monodentate chiral phosphines. (+)- and 6-dimethyl-9-phenyl-9-phos phabicyclo[3.3.1]nonanes ((+)- and (-)-9-PBNs), were prepared from 1,5 -dimethyl-1,5-cyclooctadiene, and their application to the asymmetric allylic substitution reaction proved the utility of 9-PBNs as chiral p hosphine ligands. Copyright (C) 1996 Elsevier Science Ltd