3-SPIN INTERACTION IN LIQUID-STATE NUCLEAR-MAGNETIC-RESONANCE

Authors
BRUSCHWEILER R
Citation
R. Bruschweiler, 3-SPIN INTERACTION IN LIQUID-STATE NUCLEAR-MAGNETIC-RESONANCE, The Journal of chemical physics, 105(15), 1996, pp. 6164-6167
Citations number
18
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
The Journal of chemical physics → ACNP
ISSN journal
00219606
Volume
105
Issue
15
Year of publication
1996
Pages
6164 - 6167
Database
ISI
SICI code
0021-9606(1996)105:15<6164:3IILN>2.0.ZU;2-Y
Abstract
The imaginary part of the magnetic dipole-dipole cross correlation spe ctral density in spin 1/2 systems generates a novel type of three-spin Hamiltonian with terms IizIjzIkz, IizIjxIkx and IizIjyIky and permuta tions in the spin labels i, j, k. These terms cause asymmetric positio ns of the spin multiplet components, which could not be explained by s calar J-coupling and chemical shift terms. (C) 1996 American Institute of Physics.