A series of Fe/Pt multilayers, prepared by magnetron sputtering, were
characterized by structural [x-ray diffraction (XRD), x-ray-absorption
spectroscopy, extended x-ray-absorption fine structure, TEM] and magn
etization techniques and extensively investigated by Mossbauer spectro
scopy. The Fe layer thickness varied from 3 to 60 Angstrom and that of
Pt from 5 to 39 Angstrom. The 3 Angstrom Fe/9 Angstrom Pt sample disp
lays magnetic hyperfine structure at room temperature (RT) while the 3
Fe/19 Pt sample is paramagnetic at RT, demonstrating the effect of th
e interlayer interaction. Both samples display out of plane magnetic a
nisotropy with a 39 degrees angle with respect to the normal for the f
ormer and 20 degrees for the latter. As the Fe layer thickness increas
es the magnetic vector turns to the plane. Systematic analysis of the
Mossbauer spectra of samples with increasing Fe layer thickness allowe
d the determination of the magnetic hyperfine field for each Fe monola
yer within the Fe layer slab. Hyperfine fields larger than the bulk Fe
value appear in all samples with Fe layer thickness larger than 3 A,
and display an oscillatory dependence on the distance of the correspon
ding Fe monolayer from the interface. These hyperfine field values sca
le linearly with the average interplanar distance of the Fe layer deri
ved from the refinement of the XRD data for each sample. Fe atomic mag
netic moments determined from superconducting quantum interference dev
ice magnetometry and Rutherford backscattering spectroscopy measuremen
ts are also larger than the bulk Fe value, approaching it for large Fe
layer thickness. The parameters determining the. enhancement of magne
tization in the Fe/Pt system are discussed.