Sa. Moya et al., METALLIC CARBONYL-COMPLEXES CONTAINING HETEROCYCLIC NITROGEN LIGANDS .4. COMPOUNDS OF THE TYPE [BRRE(CO)(3)(4'-R-2,2' 6',2''-TERPYRIDINE)]/, Boletin de la Sociedad Chilena de Quimica, 41(3), 1996, pp. 251-256
New complexes of the BrRe(CO)(3)(L) type have been prepared, where L a
re derivatives of the 2,2':6',2 ''-terpyridine containing in the posit
ion 4', phenyl or pyridyl group. The bidentate coordination of the het
erocyclic nitrogen ligand in a pseudo octahedral fac structure was est
ablished by using FTIR, UV-Vis and H-1-NMR spectroscopy and cyclic vol
tammetry.