INCLUSION-COMPOUNDS OF HALF-SANDWICH COMPLEXES OF IRON WITH CYCLODEXTRINS - UNPRECEDENTED LAMINAR STRUCTURES

Authors
DIAZ C ARANCIBIA A
Citation
C. Diaz et A. Arancibia, INCLUSION-COMPOUNDS OF HALF-SANDWICH COMPLEXES OF IRON WITH CYCLODEXTRINS - UNPRECEDENTED LAMINAR STRUCTURES, Boletin de la Sociedad Chilena de Quimica, 41(3), 1996, pp. 291-294
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Boletin de la Sociedad Chilena de Quimica → ACNP
ISSN journal
03661644
Volume
41
Issue
3
Year of publication
1996
Pages
291 - 294
Database
ISI
SICI code
0366-1644(1996)41:3<291:IOHCOI>2.0.ZU;2-I
Abstract
The treatment of beta- and gamma-cyclodextrins with the half-sandwich complexes of iron, afford the inclusion compounds CpFe(L(2))A-CD (beta and gamma) (A = Cl, l), L(2) = dppe, (CO)(2), dppe = Ph(2)P(CH2)(2)PP h(2), [CpFe(L(2))L']PF6 . CD (beta- and gamma-) L' = neutral donor lig ands and [(CpFe(dppe))(2)-mu-CN]PF6 . 2CD (beta and gamma-). The inclu sion compounds [CpFe(dppe)NCCH3]PF6 .gamma-CD and [CpFe(dppe)(eta(1)-d ppm)]PF6 .gamma-CD present a laminar structure.