REVISITING THE COLLISION-INDUCED LIGHT-SCATTERING SPECTRUM OF GASEOUSCH4

Authors
MEINANDER N TABISZ GC BAROCCHI F ZOPPI M
Citation
N. Meinander et al., REVISITING THE COLLISION-INDUCED LIGHT-SCATTERING SPECTRUM OF GASEOUSCH4, Molecular physics, 89(2), 1996, pp. 521-531
Citations number
38
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Molecular physics → ACNP
ISSN journal
00268976
Volume
89
Issue
2
Year of publication
1996
Pages
521 - 531
Database
ISI
SICI code
0026-8976(1996)89:2<521:RTCLSO>2.0.ZU;2-1
Abstract
The profile of the two-body collision-induced light scattering spectru m of CH4 at temperatures from 295 K to 130 K is calculated through a c lassical trajectory simulation of the collision. Free translational, b ound state, and single and double induced rotational contributions are included. The magnitudes of the dipole-quadrupole and dipole-octopole polarizabilities are found to be 0.75 Angstrom(4) and 2.7 Angstrom(5) , respectively, through comparison with experiment.