ACTIVITY-COEFFICIENT AND EXCESS GIBBS FREE-ENERGIES OF ALLYL ALCOHOL WITH TRICHLOROETHYLENE

Citation
Rv. Kumar et al., ACTIVITY-COEFFICIENT AND EXCESS GIBBS FREE-ENERGIES OF ALLYL ALCOHOL WITH TRICHLOROETHYLENE, Thermochimica acta, 287(1), 1996, pp. 7-11
Citations number
10
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00406031
Volume
287
Issue
1
Year of publication
1996
Pages
7 - 11
Database
ISI
SICI code
0040-6031(1996)287:1<7:AAEGFO>2.0.ZU;2-R
Abstract
Isobaric vapour-liquid equilibrium data have been measured for allyl a lcohol and trichlorethylene at 200, 500 and 705 Torr for ten compositi ons spread evenly over the entire liquid mole fraction range, employin g a Swietoslawski-type ebulliometer. The mole fraction composition vs. boiling point data are well represented by the Wilson model. The opti mum Wilson parameters are used to calculate the vapour compositions, a ctivity coefficients and the excess Gibbs free energy.