APPLICATION OF H-1-NOESY NMR-SPECTROSCOPY TO THE INVESTIGATION OF ION-PAIR SOLUTION STRUCTURES OF ORGANOMETALLIC COMPLEXES BY THE DETECTIONOF INTERIONIC CONTACTS

Authors
BELLACHIOMA G CARDACI G MACCHIONI A REICHENBACH G TERENZI S
Citation
G. Bellachioma et al., APPLICATION OF H-1-NOESY NMR-SPECTROSCOPY TO THE INVESTIGATION OF ION-PAIR SOLUTION STRUCTURES OF ORGANOMETALLIC COMPLEXES BY THE DETECTIONOF INTERIONIC CONTACTS, Organometallics, 15(21), 1996, pp. 4349-4351
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
21
Year of publication
1996
Pages
4349 - 4351
Database
ISI
SICI code
0276-7333(1996)15:21<4349:AOHNTT>2.0.ZU;2-F
Abstract
The interionic solution structures of trans-[Ru(PMe(3))(2)(CO)(COMe)(p z(2)-CH2)]BPh(4) and trans -[Ru-(PMe(3))(2)(CO)(COMe)(eta(2)-pz(3)-CH) ]BPh(4) have been ''directly'' investigated by the detection of interi onic contacts in H-1-NOESY NMR spectra between the protons of the orga nometallic fragments and those of the counterion. BPh(4)(-). A compari son with the solid-state structures obtained by single-crystal X-ray s tudies has been made.