SYNTHESIS AND STRUCTURE OF FREE AND COMPLEX-STABILIZED BIS(CYCLOPENTADIENYL)TELLURIUM - [ETA(1)-(ME(3)SI)(3)C5H2](2)TE AND [ETA(1)-(ME(3)SI)(3)C5H2](2)TEW(CO)(5)

Authors
TALER G WURST K SLADKY F
Citation
G. Taler et al., SYNTHESIS AND STRUCTURE OF FREE AND COMPLEX-STABILIZED BIS(CYCLOPENTADIENYL)TELLURIUM - [ETA(1)-(ME(3)SI)(3)C5H2](2)TE AND [ETA(1)-(ME(3)SI)(3)C5H2](2)TEW(CO)(5), Organometallics, 15(21), 1996, pp. 4639-4641
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
21
Year of publication
1996
Pages
4639 - 4641
Database
ISI
SICI code
0276-7333(1996)15:21<4639:SASOFA>2.0.ZU;2-M
Abstract
[eta(1)-(Me(3)Si)(3)C5H2]Te-2 (1), the first homoleptic cyclopentadien yltellurium compound, is obtained by reacting lithium tris(trimethylsi lyl)cyclopentadienide with bis(diethyldithiocarbamato)tellurium. 1 slo wly decomposes at room temperature but can be stabilized as [eta(1)-(M e(3)Si)(3)C5H2]2TeW(CO)(5) (2). 1 and 2 are structurally characterized by single-crystal X-ray diffraction.