SYNTHESIS, PHYSICAL-PROPERTIES AND X-RAY CRYSTAL-STRUCTURE OF [(DMNP)(2)(MNP)(2)SIMO12O40-CENTER-DOT-2DMF] A CHARGE-TRANSFER SALT BETWEEN ORGANIC DONOR AND POLYOXOMETALATE ACCEPTOR

Authors
ZHANG XM SHAN BZ YOU XZ FUN HK
Citation
Xm. Zhang et al., SYNTHESIS, PHYSICAL-PROPERTIES AND X-RAY CRYSTAL-STRUCTURE OF [(DMNP)(2)(MNP)(2)SIMO12O40-CENTER-DOT-2DMF] A CHARGE-TRANSFER SALT BETWEEN ORGANIC DONOR AND POLYOXOMETALATE ACCEPTOR, Polyhedron, 16(1), 1997, pp. 95-102
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
1
Year of publication
1997
Pages
95 - 102
Database
ISI
SICI code
0277-5387(1997)16:1<95:SPAXCO>2.0.ZU;2-1
Abstract
The title complex [(DMNP)(2)(MNP)(2)SiMo12O40. 2DMF] (where DMNP is Me NC(5)H(4)NMe(2), MNP is MeNC(5)H(4)NHMe and DMF is N,N-dimethyl formam ide) has been synthesized and characterized by elemental analysis, XPS , ESR and IR spectra studies. The X-ray crystal structure revealed tha t the title complex possesses a noncentrosymmetrical arrangement in th e unit cell.