5 OXIDATION-STATES IN METAL-BONDED C-4 CHAINS

Authors
BRUCE MI DENISOVICH LI LOW PJ PEREGUDOVA SM USTYNUK NA
Citation
Mi. Bruce et al., 5 OXIDATION-STATES IN METAL-BONDED C-4 CHAINS, Mendeleev communications, (5), 1996, pp. 200-201
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
5
Year of publication
1996
Pages
200 - 201
Database
ISI
SICI code
0959-9436(1996):5<200:5OIMCC>2.0.ZU;2-M
Abstract
The 36-electron diruthenium buta-1,3-diynyl complexes [Ru]C=C-C=C[Ru] [Ru = Ru(PPh(3))(2)Cp and Ru(PMe(3))(PPh(3))Cp] undergo four stepwise one-electron oxidation-reduction processes by cyclic voltammetry; some of the oxidised complexes have also been prepared by chemical oxidati on.