INFLUENCE OF TUNNELING ON THE RATIO OF THE ACTIVATION RATE CONSTANTS OF C-C AND C-H BONDS IN ETHANE BY A BARE PALLADIUM ATOM

Authors
MAMAEV VM GLORIOZOV IP PRISYAJNYUK AV USTYNYUK YA
Citation
Vm. Mamaev et al., INFLUENCE OF TUNNELING ON THE RATIO OF THE ACTIVATION RATE CONSTANTS OF C-C AND C-H BONDS IN ETHANE BY A BARE PALLADIUM ATOM, Mendeleev communications, (5), 1996, pp. 203-205
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
5
Year of publication
1996
Pages
203 - 205
Database
ISI
SICI code
0959-9436(1996):5<203:IOTOTR>2.0.ZU;2-1
Abstract
Dynamic modeling of ethane oxidative insertion to a bare palladium ato m at both C-C and C-H bonds has demonstrated the influence of quantum effects in the more growth of the rate constant of C-H bond activation compared to C-C activation.