SYNTHESIS AND FLUORESCENCE OF 2,4-DIPHENYL-1-AZAFLUORENE

Citation
Ah. Moustafa et Aa. Alahmady, SYNTHESIS AND FLUORESCENCE OF 2,4-DIPHENYL-1-AZAFLUORENE, Indian Journal of Heterocyclic Chemistry, 6(1), 1996, pp. 37-40
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
09711627
Volume
6
Issue
1
Year of publication
1996
Pages
37 - 40
Database
ISI
SICI code
0971-1627(1996)6:1<37:SAFO2>2.0.ZU;2-6
Abstract
2,4-diphenyl-1-azafluorene (3) was synthesised by the reaction of 2-ph enylmethylene indan-1-one with caynoacetamide in the presence of ammon ium acetate. Its solutions in protic solvents display a blue fluoresce nce, while in aprotic solvents a violet fluorescence was produced. The fluorescence has been quenched by concentration and proved to be acco mpanied by the formation of excited dimer of the type excimer. The kin etic rates of the quenching and the formation of the excimer were dete rmined.