Ah. Moustafa et Aa. Alahmady, SYNTHESIS AND FLUORESCENCE OF 2,4-DIPHENYL-1-AZAFLUORENE, Indian Journal of Heterocyclic Chemistry, 6(1), 1996, pp. 37-40
2,4-diphenyl-1-azafluorene (3) was synthesised by the reaction of 2-ph
enylmethylene indan-1-one with caynoacetamide in the presence of ammon
ium acetate. Its solutions in protic solvents display a blue fluoresce
nce, while in aprotic solvents a violet fluorescence was produced. The
fluorescence has been quenched by concentration and proved to be acco
mpanied by the formation of excited dimer of the type excimer. The kin
etic rates of the quenching and the formation of the excimer were dete
rmined.