The discovery of the first high-gain hydrogen recombination line (HRL)
maser in the millimeter/submillimeter spectrum of the emission-line s
tar MWC 349A requires an expansion of current paradigms about HRLs. In
this paper we reexamine the problem of non-LTE populations in recombi
ning hydrogen and specify the conditions necessary for high-gain masin
g and lasing in HRLs. To do so, we use the extensive new results on hy
drogen level populations produced by Storey & Hummer and our calculati
ons for the net (that is, line plus continuum) absorption coefficient
for HRLs. We present results for the alpha- and beta-lines whose princ
ipal quantum numbers n are between five and 100, for gas whose electro
n number density 3 less than or equal to log N-e(cm(-3))less than or e
qual to 11, at two electron temperatures, T-e = 5000 and 10,000 K. We
show that the unsaturated maser gain in an HRL is a sharp function of
N-e, and thus to achieve high-gain masing, each line requires a suffic
iently extended region over which the density is rather closely specif
ied. Saturation of masing recombination lines is a critical considerat
ion. We derive a simple equation for estimating the degree of saturati
on from the observed flux density and the interferometric and/or model
information about the amplification path length, avoiding the vague i
ssue of the solid angle of masing. We also present a qualitative way t
o approach the effects of saturation on adjacent emission lines, altho
ugh the detailed modeling is highly case-specific. We draw attention t
o another non-LTE phenomenon active in hydrogen: the overcooling of po
pulations. This occurs for HRLs with n greater than or similar to 20,
in gas where N-e less than or similar to 10(5) cm(-3). Observationally
, the HRL overcooling might manifest itself as an anomalously weak emi
ssion recombination line, or as a ''dasar,'' that is, an anomalously s
trong absorption line. In the simplest case of a homogeneous H rr regi
on, the absorption can be observed on the proper free-free continuum o
f the region, if some conditions for the line or/and continuum optical
depths are satisfied. We briefly discuss the prospects of detecting h
ydrogen masers, lasers, and dasars in several classes of Galactic and
extragalactic objects, including compact H II regions, Be or Wolf-Raye
t stars, starburst galaxies, and active galactic nuclei.