DIASTEREOSELECTIVE SYNTHESIS OF METAL CARBENE-FUNCTIONALIZED SPIROCYCLIC CARBOHYDRATES

Citation
Kh. Dotz et al., DIASTEREOSELECTIVE SYNTHESIS OF METAL CARBENE-FUNCTIONALIZED SPIROCYCLIC CARBOHYDRATES, Synlett, (10), 1996, pp. 995
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
09365214
Issue
10
Year of publication
1996
Database
ISI
SICI code
0936-5214(1996):10<995:DSOMCS>2.0.ZU;2-F
Abstract
The cycloisomerization of carbohydrate-derived butynols at a low-valen t chromium or tungsten template affords spirocyclic 2-oxacyclopentylid ene complexes which allow subsequent diastereoselective alpha-function alization.