ITA
ENG

FIRST PHOTOLYSIS OF AN ENOLIZABLE 1,4-DITHIOKETONE - PHOTOCHEMICAL STUDY OF BIS-THIOCAMPHOR

Authors

SALAMA P POIRIER M MAYA MDP ROBICHAUD J BENOIT M

Citation

P. Salama et al., FIRST PHOTOLYSIS OF AN ENOLIZABLE 1,4-DITHIOKETONE - PHOTOCHEMICAL STUDY OF BIS-THIOCAMPHOR, Synlett, (9), 1996, pp. 823

Citations number

Categorie Soggetti

Chemistry Inorganic & Nuclear

Journal title

Synlett → ACNP

ISSN journal

09365214

Issue

Year of publication

1996

Database

ISI

SICI code

0936-5214(1996):9<823:FPOAE1>2.0.ZU;2-A

Abstract

The photolysis of an enolizable 1,4-dithioketone is carried out for th e first time. When submitted to a UV radiation at 254 nm, bisthiocamph or 5 led principally and unexpectedly to the mercaptoenethione 11. A r ationalization of the result difference observed with the photolysis o f thiocamphor 1 is proposed.