AN EFFICIENT STEREOCONTROLLED SYNTHESIS OF (-)-STYPOLDIONE

Authors
ABAD A AGULLO C ARNO M CUNAT AC MESEGUER B
Citation
A. Abad et al., AN EFFICIENT STEREOCONTROLLED SYNTHESIS OF (-)-STYPOLDIONE, Synlett, (9), 1996, pp. 913
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
9
Year of publication
1996
Database
ISI
SICI code
0936-5214(1996):9<913:AESSO(>2.0.ZU;2-P
Abstract
(A)n efficient synthesis of (-)-stypoldione (3), via (-)-stypoldiol (1 ), was accomplished starting from S-(+)-carvone (4) using an IMDA reac tion, a sonochemical Barbier reaction and an acid-catalysed quinol-ter tiary alcohol cyclization as key synthetic steps.