SULFONYL ESTERS .7. THE 2ND AND 3RD SEQUENCES IN THE TRITHIOORTHOFORMATE REACTION

Authors
GINIGE KA GOEHL JE LANGLER RF
Citation
Ka. Ginige et al., SULFONYL ESTERS .7. THE 2ND AND 3RD SEQUENCES IN THE TRITHIOORTHOFORMATE REACTION, Canadian journal of chemistry, 74(9), 1996, pp. 1638-1648
Citations number
30
Categorie Soggetti
Chemistry
Journal title
Canadian journal of chemistry → ACNP
ISSN journal
00084042
Volume
74
Issue
9
Year of publication
1996
Pages
1638 - 1648
Database
ISI
SICI code
0008-4042(1996)74:9<1638:SE.T2A>2.0.ZU;2-W
Abstract
A previous report has established the intermediacy of a sulfide-sulfon ate ester in the one-pot conversion of an aryl mercaptan and a sulfona te ester into the corresponding trithioorthoformate. This report descr ibes evidence for the sequential intermediacy of a bissulfide-sulfonat e ester and a dithiosulfene in the conversion of the sulfide-sulfonate ester into the trithioorthoformate. A new sulfonate ester is shown to give the highest yield of trithioorthoformate.