The phase diagram was determined for the entire composition range of t
he system Pb(Yb1/2Nb1/2)O-3-PbZrO3. Despite the fact that both end mem
bers Pb(Yb1/2Nb1/2)O-3 and PbZrO3 are antiferroelectric, a ferroelectr
ic phase appeared for a narrow composition range, and its nature was b
riefly discussed. The phase diagram was found to consist of the three
phases, paraelectric (PE) cubic, ferroelectric (FE) tetragonal and ant
iferroelectric (AFE) orthorhombic. An insoluble region was also found
to exist.