We have equilibrated carbon-saturated Fe-Ni-Co-S melts in a San-Carlos
olivine matrix between 1350 and 1570 degrees C at 2 GPa, to measure t
he median dihedral angles of metallic core melts in a silicate mantle
matrix as a function of temperature and Sulfur fugacity. The angles in
crease from about 68 degrees for the most oxidized monosulfide liquid
solutions (metal-sulfur ratio similar to 0.97), to similar to 115 degr
ees for the most reduced metal-rich melts (M/S similar to 100), Temper
ature effects are small, These angles preclude that metallic core melt
s could have segregated efficiently from a crystalline silicate mantle
by grain boundary percolation, We suggest that core formation must ha
ve occurred from a magma ocean.