CYCLIC OXACARBENE COMPLEXES OF THE CYCLOHEPTATRIENYLMOLYBDENUM AUXILIARY MOL(2)(ETA-C7H7), L=CO OR P-DONOR LIGAND - ISOLATION AND SUBSEQUENT CYCLIZATION OF A HYDROXYVINYLIDENE INTERMEDIATE

Authors
BEDDOES RL GRIME RW HUSSAIN ZI WHITELEY MW
Citation
Rl. Beddoes et al., CYCLIC OXACARBENE COMPLEXES OF THE CYCLOHEPTATRIENYLMOLYBDENUM AUXILIARY MOL(2)(ETA-C7H7), L=CO OR P-DONOR LIGAND - ISOLATION AND SUBSEQUENT CYCLIZATION OF A HYDROXYVINYLIDENE INTERMEDIATE, Journal of the Chemical Society. Dalton transactions, (19), 1996, pp. 3893-3895
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
19
Year of publication
1996
Pages
3893 - 3895
Database
ISI
SICI code
0300-9246(1996):19<3893:COCOTC>2.0.ZU;2-E
Abstract
The cyclic oxacarbene complexes [Mo{CCH2(CH2)(n)CH2O}L(2)(eta-C7H7)]PF 6 [n = 1 or 2; L = CO, L(2) = Ph(2)PCH(2)PPh(2) or Ph(2)PCH(2)CH(2)PPh (2) (dppe)] have been synthesised and the 1-oxacyclopent-2-ylidene lig and in the derivative n = 1, L(2) = dppe shown to adopt a horizontal o rientation; the crystallographically characterised, hydroxyvinylidene complex [Mo{C=C(H)CH2CH2CH2OH}(dppe)(eta-C7H7)]PF6 is an isolable inte rmediate in the formation of [Mo{CCH2(CH2)(2)CH2O}(dppe)(eta-C7H7)]PF6 .