HIGHLY STEREOCONTROLLED SYNTHESIS OF ENANTIOMERIC 4-METHOXY TRINEMS VIA RESOLUTION OF SCALEMIC ENOL PHOSPHATES

Citation
M. Panunzio et al., HIGHLY STEREOCONTROLLED SYNTHESIS OF ENANTIOMERIC 4-METHOXY TRINEMS VIA RESOLUTION OF SCALEMIC ENOL PHOSPHATES, Tetrahedron : asymmetry, 7(10), 1996, pp. 2929-2938
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
ISSN journal
09574166
Volume
7
Issue
10
Year of publication
1996
Pages
2929 - 2938
Database
ISI
SICI code
0957-4166(1996)7:10<2929:HSSOE4>2.0.ZU;2-Q
Abstract
Stereocontrolled syntheses of 4-methoxy trinem 2 and its enantiomer 3 were achieved using the ester enolate N-trimethylsilylimine approach. The key step was the resolution of racemic enolphosphates derived from ephedrine. Copyright (C) 1996 Elsevier Science Ltd