STATIC AND DYNAMIC WETTING PROPERTIES OF THIN RUBBER FILMS

Citation
D. Long et al., STATIC AND DYNAMIC WETTING PROPERTIES OF THIN RUBBER FILMS, Langmuir, 12(21), 1996, pp. 5221-5230
Citations number
19
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
07437463
Volume
12
Issue
21
Year of publication
1996
Pages
5221 - 5230
Database
ISI
SICI code
0743-7463(1996)12:21<5221:SADWPO>2.0.ZU;2-0
Abstract
We model the statics and dynamics of wetting of liquids on thin rubber films. We show that at equilibrium the capillary forces deform soft s ubstrates, leading to undulations of the rubber film surface originati ng at the triple Line. Such deformations propagate when a liquid sprea ds on the rubber film. This induces the dissipation that may control t he spreading dynamics. We derive a general expression for this dissipa tion as a function of the viscoelastic properties of the substrate. We calculate the spreading velocities for various mechanical relaxation models. Using available mechanical relaxation data, we find that our m odel may well account for the experimental observations of Carre and S hanahan, who demonstrated the importance of viscoelastic braking effec ts.