Yp. Li et al., SIMS, RBS, AND ION CHANNELING STUDIES OF H-2(-18(+) IRRADIATED LAALO3, (100) SINGLE-CRYSTAL() OR O), Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 118(1-4), 1996, pp. 133-138
LaAlO3 is a popular single crystal substrate for epitaxial growth of Y
Ba2Cu3O7-delta (YBaCuO) high-T-c films. This research concerns the stu
dy of both irradiation and annealing of LaAlO3 (100) single crystal us
ing SIMS, RBS, acid ion channeling. It has been found that irradiation
by 50 keV 1 X 10(16) H-2(+)/cm(2) induces a lightly damaged region in
LaAlO3 to a depth of similar to 0.8 mu m. Rapid thermal annealing (RT
A) at 870 degrees C results in the annealing of most of the implant da
mage near the end of range, and the restoration of a ''perfect'' cryst
al near the surface. Whereas denser cascade collision induced by irrad
iation with the heavier O ions (200 keV 5 X 10(16) O-18(+)/cm(2)) amor
phises the material and RTA at 870 degrees C causes crystal regrow to
the surface but leaves significant crystal damage both at the end of t
he range and near the surface. The as-implanted H-2 and O-18 concentra
tion distributions were obtained with an Atomika 6500 SIMS instrument
using 10 keV Cs+ primary beam and compared with the simulated distribu
tions by TRIM-92. The diffusivities of hydrogen and oxygen in the irra
diated LaAlO3 are also reported.