KINETICS OF OXIDATION OF TRIS-(2,2'-BIPYRIDYL)COBALT(II) BY IRON(III)-2,2'-BIPYRIDYL COMPLEX - MICELLAR EFFECT OF SODIUM DODECYL-SULFATE

Authors
RAO PVS RAO GK RAMAKRISHNA K RAMBABU G SATYANARAYANA A
Citation
Pvs. Rao et al., KINETICS OF OXIDATION OF TRIS-(2,2'-BIPYRIDYL)COBALT(II) BY IRON(III)-2,2'-BIPYRIDYL COMPLEX - MICELLAR EFFECT OF SODIUM DODECYL-SULFATE, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 35(11), 1996, pp. 969-973
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical → ACNP
ISSN journal
03764710
Volume
35
Issue
11
Year of publication
1996
Pages
969 - 973
Database
ISI
SICI code
0376-4710(1996)35:11<969:KOOOTB>2.0.ZU;2-Q
Abstract
Iron(III)-2,2'-bipyridyl complex obtained, in situ, by direct mixing o f iron(III) and 2,2'-bipyridyl, oxidises \ Co(Bipy)(3)(2+) and the rea ction is markedly accelerated by sodium dodecylsulphate. The rate-[sur factant] profile exhibits a maximum. The kinetic analysis of the micel lar effect has been carried out using Berezin's approach. The binding constants of 2,2'-bipyridyl and Co(Bipy)(3)(2+) have been determined.