MOLECULAR-STRUCTURE DETERMINATION AND STUDIES ON CHEMICAL AND ELECTROCHEMICAL REDOX REACTIONS OF A CYCLIC TRISELENIDE COMPOUND, 4,7-DIMETHOXYBENZOTRISELENOLE

Authors
OGAWA S OHMIYA T KIKUCHI T KAWAI Y NIIZUMA S SATO R
Citation
S. Ogawa et al., MOLECULAR-STRUCTURE DETERMINATION AND STUDIES ON CHEMICAL AND ELECTROCHEMICAL REDOX REACTIONS OF A CYCLIC TRISELENIDE COMPOUND, 4,7-DIMETHOXYBENZOTRISELENOLE, Heterocycles, 43(9), 1996, pp. 1843-1846
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocycles → ACNP
ISSN journal
03855414
Volume
43
Issue
9
Year of publication
1996
Pages
1843 - 1846
Database
ISI
SICI code
0385-5414(1996)43:9<1843:MDASOC>2.0.ZU;2-8
Abstract
Crystalline triselenide compound, 4,7-dimethoxybenzotriselenole, was p repared and characterized by single-crystal X-ray analysis; in the uni t cell the two molecules stack each other with distorted triselenide r ings sticking out from the benzene column. Interconversion accompanyin g one-electron transfer steps between the triselenole and the correspo nding triselenolium radical cation salt has been constructed by chemic al and electrochemical treatments.