RESONANT EXCITATION-ENERGY TRANSFER IN [RH(BPY)(3)][NACR(OX)(3)]CLO4

Authors
HAUSER A RIESEN H PELLAUX R DECURTINS S
Citation
A. Hauser et al., RESONANT EXCITATION-ENERGY TRANSFER IN [RH(BPY)(3)][NACR(OX)(3)]CLO4, Chemical physics letters, 261(3), 1996, pp. 313-317
Citations number
17
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
261
Issue
3
Year of publication
1996
Pages
313 - 317
Database
ISI
SICI code
0009-2614(1996)261:3<313:RETI[>2.0.ZU;2-B
Abstract
Resonant fluorescence line narrowing of the R(1) line of the [Cr(ox)(3 )](3-) chromophore in [Rh(bpy)(3)][NaCr(ox)(3)]ClO4 at 1.6 K neither g ives rise to the usual three-line pattern nor to spectral diffusion. I nstead multi-line spectra with spacings equal to the zero-field splitt ing of the ground state are observed. This phenomenon is attributed to efficient non-radiative resonant energy transfer within the R(1) line .