S. Ortolland et al., EFFECT OF BORON-DIFFUSION ON THE HIGH-VOLTAGE BEHAVIOR OF 6H-SIC P(+)NN(+) STRUCTURES, Journal of applied physics, 80(9), 1996, pp. 5464-5468
Boron diffusion can be used to compensate the n-type layer of a p(+)nn
(+) 6H-silicon carbide structure in order to increase its high-voltage
capabilities. Measurements under reverse biases for a current range f
rom 10 to 500 mu A show that this process is very efficient for workin
g temperatures about 300 K. Indeed we obtained a voltage of 670 V for
a reverse current of 10 mu A instead of the 120 V calculated for a str
ucture without boron diffusion. Nevertheless, the breakdown voltage de
creases rapidly when the temperature increases. Capacitance measuremen
ts show that the measured doping level in the n-type layer evolves in
the same way as the temperature (it ranges from 10(13) cm(-3) at 300 K
to 10(17) cm(-3) at 500 K). A great concentration of boron seems to b
e responsible for this doping variation with temperature. Admittance s
pectroscopy reveals the presence of D centers at 0.62 eV above the val
ence band associated to boron at concentration similar or superior to
nitrogen concentration in the n-type layer. The increase of the doping
level with the temperature is responsible for this decrease of the br
eakdown voltage. (C) 1996 American Institute of Physics.