We present high-sensitivity observations of the SiO transition v=2 J=2
-1, which is known to present anomalous maser emission, together with
simultaneous observations of the v=1 J=2-1 intense maser. Only 3 stars
were previously detected in the v=2 J=2-1 transition. We present 8 ne
w detections (out of a total of 10 detected stars) and significant upp
er limits for 37 other stars, which allows for the first time a statis
tical study of this maser transition. The unexpectedly weak emission i
n this line is confirmed. There is also a clear trend favoring the emi
ssion of the v=2 J=2-1 line in S-type stars, with respect to O-rich so
urces (that are the most common emitters in the other SiO lines): the
v=2/v=1 J=2-1 line ratio is at least 10 times larger in S-type stars t
han in M-type sources. We also find a trend of the v=2 J=2-1 emission
to be relatively red-shifted, confirming a previous result for one sou
rce. The possible origin of these properties is discussed. We conclude
that the mechanism previously proposed by Olofsson et al., introducin
g the effects of line overlap between one re-vibrational transition of
SiO and another one of H2O, can explain the observed peculiarities of
the SiO v=2 J=2-1 line.