Photoluminescence of lead tungstate and its time evolution at differen
t temperatures and excitation conditions were investigated to identify
the mechanisms of radiative and nonradiative recombination in this sc
intillation crystal. Two centers responsible for short-wavelength emis
sion were revealed and characterized. The results indicated the energy
transfer between different centers to be of great importance. Red lum
inescence was shown to be useful for quality control of comparatively
perfect crystals.