USE OF DIFFERENTIAL SCANNING CALORIMETRY AND THERMOGRAVIMETRIC ANALYSIS TO CHARACTERIZE THE THERMAL-DEGRADATION OF CRYSTALLINE SUCROSE AND DRIED SUCROSE-SALT RESIDUES

Thermal degradation of pure sucrose in concentrated aqueous solution ( 100 degrees C, similar to 65 degrees Brix) in the presence of KCl, LiC l, NaI, and Na2B4O7 was investigated. Polarimetry was used to quantify sucrose degradation, and pseudo-first-order kinetic constants of init ial degradation rates were calculated. All salts significantly increas ed sucrose degradation; colored degradation products were only formed in the presence of Na2B4O7. Thermal degradation characteristics of cry stalline sucrose and dried, crystalline residues from sucrose-salt mod el solutions heated at 100 degrees C for 0 and 3 h were further invest igated by differential scanning calorimetry (DSC), thermogravimetric ( TG), and differential thermogravimetric (DTG) analyses. Rate of heatin g was 15 degrees C/min from 50 to 500 degrees C. DSC and TG studies co nfirmed the catalytic nature of salts on the thermal degradation of su crose. Salts affected thermal degradation in various ways. The initial condensation degradation reactions were more rapid than expected, and subsequent elimination reactions were slower. The thermal analysis re sults indicate that complexation between the salt and sucrose is occur ring, and further study at the molecular level is required.