NONTRADITIONAL MECHANISMS OF SOLID-PHASE ASTROCHEMICAL REACTIONS

Authors
Citation
Vi. Goldanskii, NONTRADITIONAL MECHANISMS OF SOLID-PHASE ASTROCHEMICAL REACTIONS, Kinetics and catalysis, 37(5), 1996, pp. 608-614
Citations number
54
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
00231584
Volume
37
Issue
5
Year of publication
1996
Pages
608 - 614
Database
ISI
SICI code
0023-1584(1996)37:5<608:NMOSAR>2.0.ZU;2-A
Abstract
The mechanisms of solid-phase reactions that can be directly related t o the formation of organic substances in space and their delivery to t he Earth as well as the problems of prebiotic evolution are considered . These mechanisms are molecular tunneling (the hypothesis of the cold prehistory of life), polycondensation of solid monomers in shock wave s (the problem of delivery of organic substances to the Earth with met eorites), thermal and thermal-wave explosions and oscillations of the radical concentration and temperature of cold small particles in the i rradiation fields, and mechanochemical explosions and autowave propaga tion of chemical reactions us a result of the positive feedback betwee n destruction of solids and reactions on newly formed surfaces.