FRACTAL-TIME DYNAMICS OF ELEMENTARY REACTIONS IN CONDENSED MEDIA

Authors
Citation
A. Plonka, FRACTAL-TIME DYNAMICS OF ELEMENTARY REACTIONS IN CONDENSED MEDIA, Kinetics and catalysis, 37(5), 1996, pp. 661-665
Citations number
23
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
00231584
Volume
37
Issue
5
Year of publication
1996
Pages
661 - 665
Database
ISI
SICI code
0023-1584(1996)37:5<661:FDOERI>2.0.ZU;2-C
Abstract
Fractal time describes highly intermittent self-similar temporal behav ior that does not possess a characteristic time scale to be related di rectly to the barrier crossing parameters like activation energy or tu nnelling distance. For fractal-time kinetics of any order there are, h owever, the moments of the distribution of the logarithms of lifetimes , which are directly related to the moments of the distributions of ba rrier crossing parameters during the reaction course. These distributi ons are compared with those following from interpretation of fractal-t ime equations in terms of superposition of classical patterns, which m ay be valid only for static systems (rigid matrix approximation).