A DIRUTHENIUM(II) COMPLEX CONTAINING AN UNPRECEDENTED BRIDGING S,O-BIDENTATE DIMETHYL-SULFOXIDE LIGAND

Authors
TANASE T AIKO T YAMAMOTO Y
Citation
T. Tanase et al., A DIRUTHENIUM(II) COMPLEX CONTAINING AN UNPRECEDENTED BRIDGING S,O-BIDENTATE DIMETHYL-SULFOXIDE LIGAND, Chemical communications, (20), 1996, pp. 2341-2342
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
20
Year of publication
1996
Pages
2341 - 2342
Database
ISI
SICI code
1359-7345(1996):20<2341:ADCCAU>2.0.ZU;2-0
Abstract
The diruthenium(II) complex [Ru-2(mu-Cl)(mu-H)(mu-Me(2)SO)- Cl-2(Me(2) SO)(4)]. 2CH(2)Cl(2) is prepared from [RuCl2(Me(2)SO)(4)] in methanol in the presence of Na-2(xdk) [H(2)xdk = m-xylenediamine bis(Kemp's tri acid imide)] and characterized by X-ray crystallography which reveals an unprecedented S,O-bidentate bridging Me(2)SO ligand.