EXCESS MOLAR VOLUMES OF (AN ISOMER OF BUTANOL PLUS BENZENE OR TOLUENE) AT THE TEMPERATURE 308.15 K

Authors
BHARDWAJ U MAKEN S SINGH KC
Citation
U. Bhardwaj et al., EXCESS MOLAR VOLUMES OF (AN ISOMER OF BUTANOL PLUS BENZENE OR TOLUENE) AT THE TEMPERATURE 308.15 K, Journal of Chemical Thermodynamics, 28(10), 1996, pp. 1173-1177
Citations number
15
Categorie Soggetti
Chemistry Physical
Journal title
Journal of Chemical Thermodynamics → ACNP
ISSN journal
00219614
Volume
28
Issue
10
Year of publication
1996
Pages
1173 - 1177
Database
ISI
SICI code
0021-9614(1996)28:10<1173:EMVO(I>2.0.ZU;2-H
Abstract
Excess molar volumes of (butan-1-ol, or butan-2-ol, or 2-methylpropan- 1-ol, or 2-methylpropan-2-ol + benzene, or toluene) over the entire ra nge of composition have been measured dilatometrically at the temperat ure 308.15 K. The results indicate that the branching of an alkyl grou p of butanol near the hydroxyl group makes both the hydrogen bonding a nd the electron donor-acceptor interactions between butanol and benzen e or toluene molecules less effective. (C) 1996 Academic Press Limited