Sc. Roy et al., DIRECT METHANOL FUEL-CELL CATHODES WITH SULFUR AND NITROGEN-BASED CARBON FUNCTIONALITY, Journal of the Electrochemical Society, 143(10), 1996, pp. 3073-3079
The effect of carbon functionality on the electrocatalytic performance
of carbon black-supported, Pt-based, direct methanol fuel cell cathod
es was investigated. Polarization data show that cathodes with nitroge
n and sulfur functionality have enhanced catalytic activity toward oxy
gen reduction. Transmission electron microscopy results indicate that
this behavior may be ascribed to a platinum particle size effect.