A. Brenner, CELLS WITH SODIUM-HYPOCHLORITE OR CHLORITE AND ANODES OF MAGNESIUM ORALUMINUM, Journal of the Electrochemical Society, 143(10), 1996, pp. 3133-3138
A cell composed of a chlorine oxy-ion salt, acting as the battery posi
tive, and anodes of magnesium or aluminum was found to be capable of p
roducing potentials and currents comparable to those of conventional b
atteries. However, its use would have to be limited to that of a reser
ve type of battery with a short service-life because of the chemical i
nteraction of the anodes with the electrolyte. This rate of reaction w
as considerably reduced by the presence of nitrate ion in the electrol
yte. The rate of decomposition of hypochlorite solutions on aging was
found not to be significant for their use in a reserve type of battery
. The utilization of the reactants in the magnesium-chlorine oxy-ion c
ells was about 60% on a continuous discharge. Since these cells after
being discharged would contain only a solution of common salt and a sl
urry of a metal hydroxide, they were innocuous with respect to the env
ironment. Since this characteristic might make the battery of possible
interest for a ''green'' motor vehicle, a battery was evaluated with
respect to the adaptations that would be necessary for such an applica
tion.