M. Smith et al., FLUID INCLUSION AND STABLE-ISOTOPE CONSTRAINTS ON THE GENESIS OF THE CLIGGA HEAD SN-W DEPOSIT, SW ENGLAND, European journal of mineralogy, 8(5), 1996, pp. 961-974
Samples of veins from the Cligga Head granite-hosted Sn-W deposit, S.W
. England, have been studied by microthermometry, and analysed for the
oxygen-isotope composition of quartz, cassiterite and wolframite and
the hydrogen-isotope composition of fluid inclusions. Samples of vein
quartz were also analysed for fluid-inclusion chemistry using a crush-
leach technique. Oxygen-isotope geothermometry using quartz-cassiterit
e and quartz-wolframite pairs indicates temperatures of 350 to 400 deg
rees C, although disequilibrium may be common. Coupled with fluid-incl
usion homogenisation temperatures of between 300 to 350 degrees C the
data suggests hydrothermal activity at 350 to 400 degrees C, and 0.7 t
o 1.7 kbar fluid pressure. High Th in some fluid inclusions suggests t
hat pressure may have dropped below 0.7 kbar during periods of vein di
lation. The calculated oxygen- and measured hydrogen-isotopic composit
ion of vein fluids (delta(18)O from 6.0 to 10.8%; delta D from -52 to
-22%) is consistent with an origin as fluid that had equilibrated with
granite at temperatures from approximately 500 to 300 degrees C. Crus
h-leach analyses show the inclusion fluids to be Na-K-Fe-Ca chloride b
rines with significant levels of B, F and SO4. The K/Na ratios are con
sistent with equilibration with granite at progressively lower tempera
tures. Log Br/Cl in the inclusion fluids ranges from -3.40 to -2.90, c
omparable to the ratios of modem fumarole gases, and consistent with t
he degassing of magmatic volatiles as the source of salinity.