STRUCTURAL CHEMISTRY OF ORGANOTIN FERROCENECARBOXYLIC ESTERS .1. SYNTHESIS AND SPECTROSCOPIC STUDIES ON DIALKYLTIN ESTERS OF FERROCENECARBOXYLIC ACID FCCOOH AND 1,1'-FERROCENEDICARBOXYLIC ACID FC(COOH)(2)

Authors
TAO JX XIAO WJ
Citation
Jx. Tao et Wj. Xiao, STRUCTURAL CHEMISTRY OF ORGANOTIN FERROCENECARBOXYLIC ESTERS .1. SYNTHESIS AND SPECTROSCOPIC STUDIES ON DIALKYLTIN ESTERS OF FERROCENECARBOXYLIC ACID FCCOOH AND 1,1'-FERROCENEDICARBOXYLIC ACID FC(COOH)(2), Journal of organometallic chemistry, 526(1), 1996, pp. 21-24
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
526
Issue
1
Year of publication
1996
Pages
21 - 24
Database
ISI
SICI code
0022-328X(1996)526:1<21:SCOOFE>2.0.ZU;2-1
Abstract
Dibutyltin and dioctyltin esters of ferrocenecarboxylic acid and dibut yltin ester of 1,1'-ferrocenedicarboxylic acid have been synthesized a nd characterized by IR and NMR (H-1, C-13, Sn-119) spectral data. Spec troscopic data suggest that the esters of ferrocenecarboxylic acid ado pt an oxygen-bridge dimer structure mode. The structure features four anisobidentate bridging carboxylate ligands. The ester of 1,1'-ferroce nedicarboxylic acid is five-coordinate monomer in solution.