PHOTOLUMINESCENCE PROPERTY OF TITANIUM SILICALITE-2 CATALYST AND ITS PHOTOCATALYTIC REACTIVITY FOR THE DIRECT DECOMPOSITION OF NO AT 295 K

Authors
ZHANG SG ICHIHASHI Y YAMASHITA H TATSUMI T ANPO M
Citation
Sg. Zhang et al., PHOTOLUMINESCENCE PROPERTY OF TITANIUM SILICALITE-2 CATALYST AND ITS PHOTOCATALYTIC REACTIVITY FOR THE DIRECT DECOMPOSITION OF NO AT 295 K, Chemistry Letters, (10), 1996, pp. 895-896
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
10
Year of publication
1996
Pages
895 - 896
Database
ISI
SICI code
0366-7022(1996):10<895:PPOTSC>2.0.ZU;2-U
Abstract
The titanium silicalite-2 (TS-2) catalyst exhibits a photoluminescence spectrum at around 450-550 nm as well as the distinct and characteris tic photocatalytic activity towards the direct decomposition of NO int o N-2, O-2 and N2O at 295 K under UV irradiation. XAFS and photolumine scence investigations indicated that the charge transfer excited state of the titanium oxide moieties having a tetrahetral coordination play s a significant role in the photoluminescence and photocatalytic react ivities of the TS-2 catalyst.