THE SYNTHESIS AND STRUCTURE OF A NEW-TYPE OF BOROSILICATE CAGE

Authors
FERGUSON G OLEARY BJ MURPHY DM SPALDING TR
Citation
G. Ferguson et al., THE SYNTHESIS AND STRUCTURE OF A NEW-TYPE OF BOROSILICATE CAGE, Journal of organometallic chemistry, 526(1), 1996, pp. 195-198
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
526
Issue
1
Year of publication
1996
Pages
195 - 198
Database
ISI
SICI code
0022-328X(1996)526:1<195:TSASOA>2.0.ZU;2-U
Abstract
The novel borosilicate compound [(t)BuSi{O(BC6H4Br)O}(3)Si(t)Bu], 1, w hich contains a Si(OBO)(3)Si cage, is synthesised by the reaction of t ert-butylsilanetriol with 4-bromophenylboric acid in toluene solution at reflux and structurally characterised with X-ray diffraction and sp ectroscopic techniques.