Ac. Gentile et al., CONVERGENCE AND PATH CANCELLATION IN QUANTUM MONTE-CARLO REAL-TIME PATH INTEGRATION, The Journal of chemical physics, 105(17), 1996, pp. 7613-7616
We find that poor resolution of the tails of the distribution of integ
rands obtained inhibits convergence in Monte Carlo calculation of real
time path integrals. We show that many methods previously tried to im
prove convergence neither resolve nor diminish the tails effectively.
We find that large contributions to the integrand come from paths that
have a large variance from the zero-path and/or that have few zero cr
ossings. The results of crude dampings based on where such paths are p
oorly sampled suggest that exploring cancellations of paths characteri
zed by path variance and zero crossings may be effective in improving
convergence. (C) 1996 American Institute of Physics.