5-COMPONENT EQUILIBRIA OF RING-CHAIN TAUTOMERIC MIXTURES DERIVED FROM3-AMINO-1,2-PROPANEDIOL AND AROMATIC-ALDEHYDES

Authors
LAZAR L LAKATOS AG FULOP F BERNATH G RIDDELL FG
Citation
L. Lazar et al., 5-COMPONENT EQUILIBRIA OF RING-CHAIN TAUTOMERIC MIXTURES DERIVED FROM3-AMINO-1,2-PROPANEDIOL AND AROMATIC-ALDEHYDES, Tetrahedron, 53(3), 1997, pp. 1081-1088
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
3
Year of publication
1997
Pages
1081 - 1088
Database
ISI
SICI code
0040-4020(1997)53:3<1081:5EORTM>2.0.ZU;2-Y
Abstract
In the reactions of 3-amino-1,2-propanediol with aromatic aldehydes, f ive-component ring-chain tautomeric mixtures were formed, involving ox azolidine and oxazine C-2 epimers and the corresponding Schiff base. T hese multicomponent tautomeric equilibria could be described by the eq uation log K = rho sigma(+) + K-0, used earlier for the two- and three -component equilibria relating to only oxazine or oxazolidine rings. C opyright (C) 1996 Elsevier Science Ltd