HIGHLY ENANTIOSELECTIVE TOTAL SYNTHESIS OF NATURAL EPOXYDICTYMENE - AN ALKOXY-DIRECTED CYCLIZATION ROUTE TO HIGHLY STRAINED TRANS-OXABICYCLO[3.3.0]OCTANES

Authors
PAQUETTE LA SUN LQ FRIEDRICH D SAVAGE PB
Citation
La. Paquette et al., HIGHLY ENANTIOSELECTIVE TOTAL SYNTHESIS OF NATURAL EPOXYDICTYMENE - AN ALKOXY-DIRECTED CYCLIZATION ROUTE TO HIGHLY STRAINED TRANS-OXABICYCLO[3.3.0]OCTANES, Tetrahedron letters, 38(2), 1997, pp. 195-198
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
2
Year of publication
1997
Pages
195 - 198
Database
ISI
SICI code
0040-4039(1997)38:2<195:HETSON>2.0.ZU;2-Q
Abstract
An enantioselective synthesis of (+)-epoxydictymene, which involves ef ficient construction of the strained oxabicyclo[3.3.0]octane subunit b y irradiation with iodosobenzene diacetate and iodine in cyclohexane s olution, is reported. Copyright (C) 1996 Elsevier Science Ltd