RADICAL DEUTERATION OF ALPHA-SELENYLATED-BETA-SILYLSULFOXIDES

Authors
ANGELAUD R LANDAIS Y
Citation
R. Angelaud et Y. Landais, RADICAL DEUTERATION OF ALPHA-SELENYLATED-BETA-SILYLSULFOXIDES, Tetrahedron letters, 38(2), 1997, pp. 233-236
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
2
Year of publication
1997
Pages
233 - 236
Database
ISI
SICI code
0040-4039(1997)38:2<233:RDOA>2.0.ZU;2-5
Abstract
The deuteration of alpha-selenylated-beta-silylsulfoxides and alpha-se lenylated-beta-tert-butylsulfoxides has been shown to lead, with good levels of diastereocontrols to the formation of syn isomers irrespecti ve of the stereochemistry of the sulfinyl precursors. Our results have been rationalized using transition state models which parallel the Fe lkin-Anh model. Copyright (C) 1996 Elsevier Science Ltd