SYNTHESIS AND CHARACTERIZATION OF BE(II) AND MG(II) COMPLEXES OF 3-HALOLAWSONEMONOXIMES

Citation
Sd. Gaikwad et al., SYNTHESIS AND CHARACTERIZATION OF BE(II) AND MG(II) COMPLEXES OF 3-HALOLAWSONEMONOXIMES, Synthesis and reactivity in inorganic and metal-organic chemistry, 26(9), 1996, pp. 1477-1487
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
00945714
Volume
26
Issue
9
Year of publication
1996
Pages
1477 - 1487
Database
ISI
SICI code
0094-5714(1996)26:9<1477:SACOBA>2.0.ZU;2-G
Abstract
A series of six new complexes of beryllium(II) and of magnesium(II) wi th 3-chloro, 3-bromo and 3-iodo derivatives of lawsonemonoxime (2-hydr oxy-1,4-naphathalenedione-1-oxime) of the type [BeL(OH)](2).2H(2)O and [MgL(2)(H2O)(2)], where L represents the anion of 3-halolawsonemonoxi me, have been prepared and characterised on the basis of elemental ana lyses, thermogravimetric analyses, molar conductance, infrared spectra and electronic spectra. A dimeric structure for the Be(II) complexes and an octahedral geometry for the Mg(II) complexes has been suggested .