SYNTHESIS AND CRYSTAL-STRUCTURE OF A FLUOROALUMINOPHOSPHATE WITH OPENFRAMEWORK - AL-3(PO4)(3)F-2, N2C4H14

Authors
RENAUDIN J LOISEAU T TAULELLE F FEREY G
Citation
J. Renaudin et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF A FLUOROALUMINOPHOSPHATE WITH OPENFRAMEWORK - AL-3(PO4)(3)F-2, N2C4H14, Comptes rendus de l'Academie des sciences. Serie II. Mecanique, physique, chimie, astronomie, 323(8), 1996, pp. 545-553
Citations number
12
Categorie Soggetti
Multidisciplinary Sciences
Journal title
Comptes rendus de l'Academie des sciences. Serie II. Mecanique, physique, chimie, astronomie → ACNP
ISSN journal
12518069
Volume
323
Issue
8
Year of publication
1996
Pages
545 - 553
Database
ISI
SICI code
1251-8069(1996)323:8<545:SACOAF>2.0.ZU;2-H
Abstract
Al-3(PO4)(3)F-2, N2C4H14 is obtained by hydrothermal synthesis using 1 ,4-diaminobutane as a template. Its structure is related to the ULM-3 type fluorometallophosphates: it is built up from corner-linked [Al-3( PO4)(3)F-2] units composed of three (PO4) tetrahedra, two (AIO(4)F) tr igonal bipyramids and one (AlO4F2) octahedron. The subnetwork of the 1 ,4-diammoniumbutane cations induces a non-centric symmetry. Crystal da ta: orthorhombic, space group Pbc2(1), a = 10.023(2) Angstrom, b = 18. 180(3) Angstrom, c = 15.841(3) Angstrom, V = 2,886.5 Angstrom(3), 2 = 8, R(F) = 2.84%, 4,263 observed reflections [F > 4 sigma(F)].